Bright orange/red-emitting rhodium(III) and iridium(III) complexes: tridentate N^C^N-cyclometallating ligands lead to high luminescence efficiencies.
نویسندگان
چکیده
Rhodium(III) complexes rarely display strong phosphorescence, in contrast to well-known iridium(III) complexes with cyclometallating ligands. This study shows how 1,3-bis(1-isoquinolyl)benzene cyclometallates to Rh(III) through N^C^N-coordination to give complexes with unprecedented phosphorescence quantum yields at room temperature. Their highly emissive Ir(III) analogues are also described.
منابع مشابه
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ورودعنوان ژورنال:
- Dalton transactions
دوره 42 29 شماره
صفحات -
تاریخ انتشار 2013